Activation, Deactivation, and Poisoning of Catalysts - download pdf or read online

By John B. Butt

ISBN-10: 0121476952

ISBN-13: 9780121476953

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Sample text

Their views parallel the views of those who favor the phenomenological description of systems of constant catalytic activity, as opposed to mechanistic descriptions. These differing viewpoints for systems of constant activity have been voiced in the literature (5, 26). Under the title of phenomenological description, we shall explore some of the mathematical forms of the deactivation function used in the literature. As will become evident, the blend of theory and empiricism varies consider­ ably among the different investigators.

React. , Proc. Eur. , 4th, 1968, p. 265 (1971). T. Uchijima, J. M. Herrmann, Y. Inoue, R. L. , J. B. Butt, and J. B. Cohen, J. Catal. 50, 464(1977). R. Van Hardeveld and F. Hartog, Surf. Sei. 15, 189 (1969); Adv. Catal. 22, 76 (1972). A. Wheeler, in "Catalysis" (P. H. ), Vol. 2, p. 105. Reinhold, New York, 1955. 11. 12. 13. 14. 15. 16. 17. 18. CHAPTER 2 Mathematical Description of Deactivating Systems Some aspire to gain immortality through their work. I want to be immortal by not dying. Woody Allen The approach to be taken here is largely an extension of that used by catalytic chemists endeavoring to understand a reaction taking place on a heterogeneous catalyst.

R. Soc. London. 124, 55 (1834). S. Fuentes and J. C. S. S. Faraday I 74, 174 (1978). S. J. Gregg and K. S. W. " Academic Press, New York, 1967. W. B. Innes, in "Experimental Methods in Catalysis Research" (R. B. ), Chap. 2. Academic Press, New York, 1968. H. Pines and W. O. Haag, J. Am. Chem. Soc. 82, 2471 (1960). P. A. Sermon and G. C. Bond, Catal. Rev. 8, 211 (1973). M. Shelef, K. Otto, and N. C. Otto, Adv. Catal. 27, 311 (1978). S. Szepe and O. Levenspiel, Chem. React. , Proc. Eur. , 4th, 1968, p.

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Activation, Deactivation, and Poisoning of Catalysts by John B. Butt

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